Master Trainers
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Every skill has one trainer who is able to train you to reach 100 in that skill. They are sometimes called the Secret Masters. Here are their specialties, names, and locations:

Acrobatics Senyndie Vivec, Arena Fighters Quarters
Alchemy Abelle Chriditte Valenvaryon, Propylon Chamber
Alteration Seryne Relas Tel Branor, Seryne Relas's House
Armorer Sirollus Saccus Ebonheart, Hawkmoth Legion Garrison
Athletics Adibael Hainnabibi Kaushtababi Camp, Adibael's Yurt
Axe Aldhedil Elf-Hewer, Falensarano, Upper Level
Block Shardie Buckmoth Legion Fort (in the courtyard)
Blunt weapon Ernse Llervu Vivec, The Abbey of St. Delyn the Wise
Conjuration Methal Seran Ald'ruhn, Temple
Destruction Leles Birian Ascadian Isles Region (on the road east of Piernette's Farmhouse)
Enchant Qorwynn Indoranyon (inside)
Hand-to-hand - Taren Omothan Holamayan Monastery
Heavy armor Seanwen Vivec, Arena Fighters Training
Illusion Erer Darothril Sadrith Mora, Dirty Muriel's Cornerclub
Light armor Aerin Maar Gan, Andus Tradehouse
Long blade Ulms Drathan Molag Mar, Armigers Stronghold
Marksman Missun Akin Falasmaryon, Missun Akin's Hut
Medium armor Cinia Urtius not in game some would have it that she should be on the boat docked at Tel Fyr. Place her where you wish by using the console (PlaceAtPC "Cinia Urtius" 1,20,1)
Mercantile Ababael Timsar-Dadisun Zainab Camp, Ababael Timsar-Dadisun's Yurt
Mysticism Ardarume Sadrith Mora, Gateway Inn: West Wing
Restoration Yakin Bael Vos, Vos Chapel
Security Hecerinde Balmora, Hecerinde's House
Short blade Todwendy Balmora, Lucky Lockup
Sneak Wadarkhu Gnaar Mok, Dreugh-jigger's Rest
Spear Mertis Falandas Ghostgate, Tower of Dusk Lower Level
Speechcraft Skink-in-Tree's-Shade - Sadrith Mora, Wolverine Hall: Mage's Guild
Unarmored Khargol gro-Boguk Dagon Fel, Vacant Tower