Master Trainers
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Every skill has one trainer who is able to train you to reach 100 in that skill. They are sometimes called the Secret Masters. Here are their specialties, names, and locations:

Acrobatics -- Senyndie -- Vivec, Arena Fighters Quarters
Alchemy -- Abelle Chriditte -- Valenvaryon, Propylon Chamber
Alteration -- Seryne Relas -- Tel Branor, Seryne Relas's House
Armorer -- Sirollus Saccus -- Ebonheart, Hawkmoth Legion Garrison
Athletics -- Adibael Hainnabibi -- Kaushtababi Camp, Adibael's Yurt
Axe -- Aldhedil Elf-Hewer, Falensarano, Upper Level
Block -- Shardie -- Buckmoth Legion Fort (in the courtyard)
Blunt weapon -- Ernse Llervu -- Vivec, The Abbey of St. Delyn the Wise
Conjuration -- Methal Seran -- Ald'ruhn, Temple
Destruction -- Leles Birian -- Ascadian Isles Region (on the road east of Piernette's Farmhouse)
Enchant -- Qorwynn -- Indoranyon (inside)
hand-to-hand -- Taren Omothan -- Holamayan Monastery
Heavy armor -- Seanwen -- Vivec, Arena Fighters Training
Illusion -- Erer Darothril -- Sadrith Mora, Dirty Muriel's Cornerclub
Light armor -- Aerin -- Maar Gan, Andus Tradehouse
Long blade -- Ulms Drathan -- Molag Mar, Armigers Stronghold
Marksman -- Missun Akin -- Falasmaryon, Missun Akin's Hut
Medium armor -- Cinia Urtius -- not in game -- some would have it that she should be on the boat docked at Tel Fyr. Place her where you wish by using the console (PlaceAtPC "Cinia Urtius" 1,20,1)
Mercantile -- Ababael Timsar-Dadisun -- Zainab Camp, Ababael Timsar-Dadisun's Yurt
Mysticism -- Ardarume -- Sadrith Mora, Gateway Inn: West Wing
Restoration -- Yakin Bael -- Vos, Vos Chapel
Security -- Hecerinde -- Balmora, Hecerinde's House
Short blade -- Todwendy -- Balmora, Lucky Lockup
Sneak -- Wadarkhu -- Gnaar Mok, Dreugh-jigger's Rest
Spear -- Mertis Falandas -- Ghostgate, Tower of Dusk Lower Level
Speechcraft -- Skink-in-Tree's-Shade -- Sadrith Mora, Wolverine Hall: Mage's Guild
Unarmored -- Khargol gro-Boguk -- Dagon Fel, Vacant Tower